环氧乙烷是用作聚酯PET等的原料。工业上生产环氧乙烷采用以银为催化剂。生产方法采用乙烯直接氧化法,该法根据选择的氧化剂不同而分为空气法(以空气中氧作氧化剂)及氧气法(以纯氧作氧化剂)。无论空气法或氧气法,所用催化剂的初始选择性均为80~83%。采用氧气法时由于氧气可带入系统一部分氩等惰性气体。副反应是乙烯直接氧化生成二氧化碳,因此,氩等惰性气体与二氧化碳在循环气中造成累积,超过一定含量时,就要影响催化剂的活性与选择性。
国标采用热导检测器,然而普通的热导灵敏度低,想要测定10ppm的二氧化碳绝非易事,需要采用高灵敏度的TCD,价格高昂,无法普及。浩瀚色谱,研制带反吹系统的甲烷转化炉氢火焰检测器测定环氧乙烷中微量的二氧化碳,定量准确,灵敏度高,结果满意。
名称:便携式甲烷转化炉
型号:HH-790CH4-GC
适合于:安捷伦4890. 5890, 6890, 7890, 7820, 8860, 8890气相色谱仪上
浩瀚色谱研制生产:外置式甲烷转化器,具有小巧玲珑,方便携带,安装简单(用户可完成安装),集成化高(含气路系统,进样系统,温控系统,分离系统),可扩展二维/多维系统,反吹,切割系统。一机多用,实用价值高。
Ethylene oxide is used as a raw material for polyester, PET, and other materials. The industrial production of ethylene oxide uses silver as a catalyst. The production method adopts ethylene direct oxidation method, which is divided into air method (using oxygen in the air as the oxidant) and oxygen method (using pure oxygen as the oxidant) according to the selected oxidant. The initial selectivity of the catalysts used, regardless of the air method or oxygen method, is 80-83%. When using the oxygen method, some inert gases such as argon can be introduced into the system. The side reaction is the direct oxidation of ethylene to produce carbon dioxide. Therefore, inert gases such as argon accumulate with carbon dioxide in the circulating gas. When the content exceeds a certain level, it will affect the activity and selectivity of the catalyst.
The national standard uses thermal conductivity detectors, but ordinary thermal conductivity detectors have low sensitivity. It is not easy to measure 10ppm of carbon dioxide, and high sensitivity TCDs are required, which are expensive and cannot be widely used. Haohan chromatography, developed a methane conversion furnace hydrogen flame detector with a backflow system to determine trace amounts of carbon dioxide in ethylene oxide, with accurate quantification, high sensitivity, and satisfactory results.
Name: Portable methane conversion furnace
Model: HH-790CH4-GC
Suitable for: Agilent 4890, 5890, 6890, 7890, 7820, 8860, 8890 gas chromatographs
Haohan Chromatography Development and Production: External methane converter, small and exquisite, easy to carry, easy to install (user can complete installation), highly integrated (including gas path system, injection system, temperature control system, separation system), expandable two-dimensional/multi-dimensional system, backflow, cutting system. One machine is versatile and has high practical value.